Which statement describes cis-trans isomerism?

Study for the IMAT Chemistry Exam. Access flashcards and multiple choice questions; hints and explanations included for each question. Prepare effectively for your exam.

Multiple Choice

Which statement describes cis-trans isomerism?

Explanation:
Cis-trans isomerism is a type of stereoisomerism that arises because rotation around a bond is restricted, so the spatial arrangement of substituents can be fixed rather than freely interchanging. This restriction happens most clearly with a carbon–carbon double bond, where rotation is not possible, and in cyclic compounds where the ring itself blocks rotation. If each carbon of the double bond (or the ring) bears different substituents, two distinct arrangements exist: substituents on the same side (cis) or on opposite sides (trans). Because the two forms have the same connectivity and the same molecular formula, they are stereoisomers rather than structural isomers. So the best description is that cis-trans isomerism is a form of stereoisomerism arising from restricted rotation around a bond. It’s not about structural connectivity changes, it’s not limited to cyclohexane, and it doesn’t involve different formulas.

Cis-trans isomerism is a type of stereoisomerism that arises because rotation around a bond is restricted, so the spatial arrangement of substituents can be fixed rather than freely interchanging.

This restriction happens most clearly with a carbon–carbon double bond, where rotation is not possible, and in cyclic compounds where the ring itself blocks rotation. If each carbon of the double bond (or the ring) bears different substituents, two distinct arrangements exist: substituents on the same side (cis) or on opposite sides (trans). Because the two forms have the same connectivity and the same molecular formula, they are stereoisomers rather than structural isomers.

So the best description is that cis-trans isomerism is a form of stereoisomerism arising from restricted rotation around a bond. It’s not about structural connectivity changes, it’s not limited to cyclohexane, and it doesn’t involve different formulas.

Subscribe

Get the latest from Examzify

You can unsubscribe at any time. Read our privacy policy